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Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups
(MDPI, 2015)The synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, ... -
Natural Coumarins: QSTR Approaches Regarding Their Genotoxicity
(MDPI, 2015)Coumarins are a group of phytochemicals with multiple applications in different fields, such as food and medicine. Many of their benefits are based on the different activities that they display, within which stand antioxidant ... -
Structural Modifications on Natural-based Products: Synthetic Strategies and Biological Applications
(MDPI, 2015)Coumarins are a class of heterocyclic compounds present in a significant quantity in several plants. The simplest coumarin, a benzene ring fused with a pyran-2-one heterocycle, was first discovered in the 19th century and ... -
H-Bonded Polymerisation of Alternate Δ and Λ Metallohelicates
(MDPI, 2015)he neutral cadmium(II) complex Cd(HL)2 (H2L = 2-[(1H-imidazol-2-yl)methyleneamino]phenol) is chiral and it can be considered as a simple metallohelicate, with its corresponding Δ and Λ enantiomers. In the solid state, its ... -
Theoretical Study of the Solvent Effect on the properties of Indole‑Cation‑Anion Complexes
(MDPI, 2015)The properties of ternary indole-cation-anion (IMX) complexes are theoretically studied as simplified models of real systems in which some of the fragments used are parts of bigger and complicated structures, like proteins. ...
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