Now showing items 1-7 of 7

    • Attainment of Pentagonal-Bipyramidal LnIII Complexes from a Planar Pentadentate Ligand 

      Corredoira Vázquez, Julio; Fondo Busto, María Matilde; Sanmartín Matalobos, Jesús; García Deibe, Ana María (MDPI, 2020)
      The search for mononuclear lanthanoid-based single-ion magnets (SIMs) has increased the interest in some coordination environments with low coordination numbers, in combination with an axial symmetry, as they could maximize ...
    • Computational and Experimental Studies Into the Conformations of a Triptycene-Based Ditopic Ligand 

      Sanmartín Matalobos, Jesús; García Deibe, Ana María; Amoza Dávila, Martín; Fondo Busto, María Matilde; Mota, Antonio J.; Bhowmick, Sourav; Das, Neeladri (MDPI, 2015)
      We present a combined computational and experimental study of the possible conformations adopted by a ditopic Schiff base ligand based on triptycene. We have performed DFT calculations on a Y-shaped Schiff base ligand ...
    • Exploring the Chelating Potential of an Easily Synthesized Schiff Base for Copper Sensing 

      Sanmartín Matalobos, Jesús; García Deibe, Ana María; Zarepour Jevinani, Morteza; Aboal Somoza, Manuel; Bermejo Barrera, María del Pilar; Fondo Busto, María Matilde (MDPI, 2020)
      The present study deals with the investigation of Cu2+, Ni2+ and Pd2+ chelating potential of the Schiff base, (E)-N-(2-((2-hydroxybenzylidene)amino)benzyl)-4-methylbenzenesulfonamide (H2SB). Crystal structures of Ni(HSB)2, ...
    • A heteronuclear ZnGd complex as a potential contrast agent for magnetic resonance imaging 

      Fondo Busto, María Matilde; Corredoira Vázquez, Julio; García Deibe, Ana María; Sanmartín Matalobos, Jesús; Iglesias Rey, Ramón; Taboada Antelo, Pablo (MDPI, 2016)
      A new ligand H3L, with internal compartments for allocating 3d metal ions and external donors to bind 4f ions, was synthesized and completely characterized. Reaction of H3L with zinc(II) and gadolin ium(III) salts allows ...
    • Imine-tetrahydroquinazoline tautomerism in a tosilated Schiff base 

      García Deibe, Ana María; Portela García, Cristina; Sanmartín Matalobos, Jesús; Fondo Busto, María Matilde (MDPI, 2010)
      Condensation of the selectively tosilated N-(2-aminobenzyl)-4-methylbenzenesulfonamide with 2-hydroxybenzaldehyde gives rise to (E)-N-(2-(2- hydroxybenzylideneamino)benzyl)-4-methylbenzenesulfonamide in the solid state, ...
    • Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups 

      González Riopedre, Gustavo; Fernández García, María Isabel; González Noya, Ana María; Pedrido Castiñeiras, Rosa María; Rodríguez Silva, Laura; Maneiro Maneiro, Marcelino (MDPI, 2015)
      The synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, ...
    • Taking Advantage of the Coordinative Behavior of a Tridentate Schiff Base Ligand towards Pd2+ and Cu2+ 

      Sanmartín Matalobos, Jesús; Fondo Busto, María Matilde; Zarepour Jevinani, Morteza; García Deibe, Ana María (MDPI, 2019)
      We have explored the suitability of an O,N,N–donor Schiff base (H2SB) for obtaining dinuclear complexes with heavy metal ions such as Cu2+, Zn2+, Ni2+, and Co2+ (borderline acids) as well as Pd2+ and Cd2+ (soft acids). ...

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