CIQUS-Artigos
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Studying an antiaromatic polycyclic hydrocarbon adsorbed on different surfaces
(Springer Nature, 2018-03-22)Antiaromatic and open-shell molecules are attractive because of their distinct electronic and magnetic behaviour. However, their increased reactivity creates a challenge for probing their properties. Here, we describe the ... -
Rhodium(III)‐Catalyzed Annulation of 2‐Alkenylanilides with Alkynes via C‐H Activation: a Direct Access to 2‐substituted Indolines
(Wiley, 2018-05-04)A Rh(III) complex featuring an electron‐deficient η5‐cyclopentadienyl ligand catalyzes an unusual annulation between alkynes and 2‐alkenylanilides, to form synthetically appealing 2‐substituted indolines. Formally, the ... -
Self-Assembly of Silver Metal Clusters of Small Atomicity on Cyclic Peptide Nanotubes
(American Chemical Society, 2015-10-06)Subnanometric noble metal clusters, composed by only a few atoms, behave like molecular entities and display magnetic, luminescent and catalytic activities. However, non-covalent interactions of molecular metal clusters, ... -
Anion recognition and induced self-assembly of an alpha,gamma-cyclic peptide to form spherical clusters
(Wiley, 2016-03-21)A cyclic octapeptide composed of hydroxy-functionalized γ-amino acids folds in a "V-shaped" conformation that allows the selective recognition of anions such as chloride, nitrate, and carbonate. The process involves the ... -
Self-assembling alfa,gamma-cyclic peptides that generate cavities with tunable properties
(Royal Society of Chemistry, 2016-01-01)The design and synthesis of β-sheet-based self-assembling cyclic peptides with tunable cavities is described. The incorporation of a γ-amino acid with a hydroxyl group at C2 allows the incorporation of different groups ...
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