Browsing CIQUS-Artigos by Subject "Enantioselectivity"
Now showing items 1-3 of 3
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Directed self-assembly of trimeric DNA-bindingchiral miniprotein helicates
(Frontiers Media, 2018)We propose that peptides are highly versatile platforms for the precise design of supramolecular metal architectures, and particularly, for the controlled assembly of helicates. In this context, we show that the bacteriophage ... -
Highly Enantioselective Cobalt‐Catalyzed (3+2) Cycloadditions of Alkynylidenecyclopropanes
(Wiley, 2021)Low‐valent cobalt complexes equipped with chiral ligands can efficiently promote highly enantioselective (3+2) cycloadditions of alkyne‐tethered alkylidenecyclopropanes. The annulation allows to assemble bicyclic systems ... -
Synergistic gold and enamine catalysis: intermolecular α-alkylation of aldehydes with allenamides
(Royal Society of Chemistry, 2016-01-08)Aldehydes can be α-alkylated with allenamides by the combined action of an organocatalyst and a gold complex. The reaction requires the simultaneous generation of an enamine and a gold-activated allenamide. Importantly, ...