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    • Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes 

      Casanova González, Noelia; Esteruelas, Miguel A.; Larramona, Carmen; Mascareñas Cid, José Luis; Gulías Costa, Moisés (American Chemical Society, 2015-12-31)
      The amide-directed synthesis of five-coordinate osmium alkylidene derivatives from alkynes is reported. These types of complexes, which have been elusive until now because of the tendency of osmium to give hydride alkylidyne ...





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