Recent Submissions

  • Vinyl Ruthenium Carbenes: Valuable Intermediates in Catalysis 

    Padín Santos, Damián; Varela Carrete, Jesús Ángel; Saá Rodríguez, Carlos (Springer, 2017)
    Vinyl ruthenium carbenes are easily prepared from the neutral Ru(II) complex Cp*RuCl(cod) in the presence of functionalized alkynes and diazoalkanes. These intermediates have been proposed for several transformations in ...
  • Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates 

    Varela Carrete, Jesús Ángel; González Rodríguez, Carlos; Saá Rodríguez, Carlos (Springer, 2014)
    Vinylidenes are high-energy tautomers of terminal alkynes and they can be stabilized by coordination with transition metals. The resulting metal-vinylidene species have interesting chemical properties that make their ...

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