Metal-Catalyzed annulations through activation and cleavage of C−H bonds
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Title: | Metal-Catalyzed annulations through activation and cleavage of C−H bonds |
Author: | Gulías Costa, Moisés Mascareñas Cid, José Luis |
Affiliation: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares Universidade de Santiago de Compostela. Departamento de Química Orgánica |
Subject: | C−H activation | Cycloaddition | Heterocycles | Homogeneous catalysis | Transition metals | |
Date of Issue: | 2016-06-22 |
Publisher: | WILEY-VCH Verlag GmbH |
Citation: | M. Gulías, J. L. Mascareñas, Angew. Chem. Int. Ed. 2016, 55, 11000 |
Abstract: | The exponential increase in the number of catalytic transformations that involve a metal-promoted activation of hitherto considered inert C−H bonds is promoting a fundamental change in the field of synthetic chemistry. Although most reactions involving C−H activations consist of simple functionalizations or additions, recent years have witnessed an upsurge in related transformations that can be formally considered as cycloaddition processes. These transformations are particularly appealing from a synthetic perspective because they allow the conversion of readily available substrates into highly valuable cyclic products in a rapid and sustainable manner. In many cases, these annulations involve the formation of metallacyclic intermediates that resemble those proposed for standard metal-catalyzed cycloadditions of unsaturated precursors |
Description: | NOTICE: This is the peer reviewed version of the following article: Moisés Gulías* and José L. Mascareñas* (2016), Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds. Angew. Chem. Int. Ed., 55, 11000-11019 [doi:10.1002/anie.201511567 (International
Edition), 10.1002/ange.201511567 (German
Edition)]. This article may be used for noncommercial purposes in accordance with Wiley Terms and Conditions for self-archiving |
Publisher version: | http://dx.doi.org/10.1002/anie.201511567 |
URI: | http://hdl.handle.net/10347/14870 |
DOI: | 10.1002/anie.201511567 |
Rights: | © WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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