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dc.contributor.authorGulías Costa, Moisés
dc.contributor.authorMascareñas Cid, José Luis
dc.identifier.citationM. Gulías, J. L. Mascareñas, Angew. Chem. Int. Ed. 2016, 55, 11000
dc.identifier.otherE-ISSN 1521-3773
dc.descriptionNOTICE: This is the peer reviewed version of the following article: Moisés Gulías* and José L. Mascareñas* (2016), Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds. Angew. Chem. Int. Ed., 55, 11000-11019 [doi:10.1002/anie.201511567 (International Edition), 10.1002/ange.201511567 (German Edition)]. This article may be used for noncommercial purposes in accordance with Wiley Terms and Conditions for self-archiving
dc.description.abstractThe exponential increase in the number of catalytic transformations that involve a metal-promoted activation of hitherto considered inert C−H bonds is promoting a fundamental change in the field of synthetic chemistry. Although most reactions involving C−H activations consist of simple functionalizations or additions, recent years have witnessed an upsurge in related transformations that can be formally considered as cycloaddition processes. These transformations are particularly appealing from a synthetic perspective because they allow the conversion of readily available substrates into highly valuable cyclic products in a rapid and sustainable manner. In many cases, these annulations involve the formation of metallacyclic intermediates that resemble those proposed for standard metal-catalyzed cycloadditions of unsaturated precursors
dc.description.sponsorshipSpanish MINECO. Grant Number: SAF2013-41943-R. ERDF. European Research Council. Grant Number: 340055. Xunta de Galicia. Grant Numbers: GRC2013-041, 2015-CP082
dc.publisherWILEY-VCH Verlag GmbH
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SAF2013-41943-R/ES/HERRAMIENTAS SINTETICAS EN QUIMICA BIOLOGICA. NUEVAS ESTRATEGIAS MOLECULARES PARA EL TRATAMIENTO Y DIAGNOSTICO DE CANCERES
dc.rights© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
dc.subjectC−H activation
dc.subjectHomogeneous catalysis
dc.subjectTransition metals
dc.subject.classificationMaterias::Investigación::23 Química::2302 Bioquímica
dc.titleMetal-Catalyzed annulations through activation and cleavage of C−H bonds
dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánica

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