• Novel Cd (II) Coordination Polymers Afforded with EDTA or Trans-1,2-Cdta Chelators and Imidazole, Adenine, or 9-(2-Hydroxyethyl) Adenine Coligands 

  Belmont Sánchez, Jeannette Carolina; García Rubiño, María Eugenia; Frontera, Antonio; Matilla Hernández, Antonio; Castiñeiras Campos, Alfonso; Niclós Gutiérrez, Juan (MDPI, 2020)

  Three mixed-ligands of Cd(II) coordination polymers were unintentionally obtained: {[Cd(µ3-EDTA)(Him)·Cd(Him)(H2O)2]·H2O}n (1), {[Cd(µ4-CDTA)(Hade)·Cd(Hade)2]}n (2), and {[Cd(µ3-EDTA)(H2O)·Cd(H9heade)(H2O)]·2H2O}n (3), ...

• Anion–Cation Recognition Pattern, Thermal Stability and DFT-Calculations in the Crystal Structure of H2dap[Cd(HEDTA)(H2O)] Salt (H2dap = H2(N3,N7)-2,6-Diaminopurinium Cation) 

  Belmont Sánchez, Jeannette Carolina; Ruiz González, Noelia; Frontera, Antonio; Matilla Hernández, Antonio; Castiñeiras Campos, Alfonso; Niclós Gutiérrez, Juan (MDPI, 2020)

  The proton transfer between equimolar amounts of [Cd(H2EDTA)(H2O)] and 2,6-diaminopurine (Hdap) yielded crystals of the out-of-sphere metal complex H2(N3,N7)dap[Cd(HEDTA)(H2O)]·H2O (1) that was studied by single-crystal ...

• Exploring the Chelating Potential of an Easily Synthesized Schiff Base for Copper Sensing 

  Sanmartín Matalobos, Jesús; García Deibe, Ana María; Zarepour Jevinani, Morteza; Aboal Somoza, Manuel; Bermejo Barrera, María del Pilar; Fondo Busto, María Matilde (MDPI, 2020)

  The present study deals with the investigation of Cu2+, Ni2+ and Pd2+ chelating potential of the Schiff base, (E)-N-(2-((2-hydroxybenzylidene)amino)benzyl)-4-methylbenzenesulfonamide (H2SB). Crystal structures of Ni(HSB)2, ...

• Core-Shell Palladium/MOF Platforms as Diffusion-Controlled Nanoreactors in Living Cells and Tissue Models 

  Martínez González, Raquel; Carrillo Carrión, Carolina; Destito, Paolo; Álvarez Lorenzo, Aitor; Tomás Gamasa, María; Pelaz García, Beatriz; López García, Fernando; Mascareñas Cid, José Luis; Pino González de la Higuera, Pablo Alfonso del (Cell Press, 2020)

  Translating the potential of transition metal catalysis to biological and living environments promises to have a profound impact in chemical biology and biomedicine. A major challenge in the field is the creation of ...

• A novel zinc(II) complex with the ligand 2,20,200-(1,4,7-triazanonane-1,4,7-triyl)- triacetate (NOTA) 

  Pereira García, Iria; Macías Luaces, Alejandro Alberto; Bastida de la Calle, María Rufina; Valencia Matarranz, Laura (Int Union Crystallography, 2009)

  The zinc(II) complex with NOTA [2,20 ,200-(1,4,7-triazanonane1,4,7-triyl)triacetate] has previously been synthesized and studied in solution, but was not isolated. The corresponding title ZnII complex pentasodium(I) ...

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