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Unha enxeñeira ou científica en cada cole
(Universidade de Vigo, Servizo de PublicaciónsUniversidade de Santiago de CompostelaUniversidade da Coruña, 2017)
Nesta comunicación, presentamos o proxecto Unha enxeñeira ou científica en cada cole organizado pola Oficina de Igualdade de Xénero da Universidade de Santiago de Compostela (USC) en colaboración co Concello de Santiago ...
Computational and Experimental Studies Into the Conformations of a Triptycene-Based Ditopic Ligand
(MDPI, 2015)
We present a combined computational and experimental study of the possible conformations adopted by a ditopic Schiff base ligand based on triptycene. We have performed DFT calculations on a Y-shaped Schiff base ligand ...
Synthesis and Characterization of a New Triptycene-Based Tripod
(MDPI, 2015)
Herein, we report an efficient and facile synthesis of a new triptycene based tripodal ligand containing both imine functionality and phenolic pendant arms. This tripodal unit is a potential building block for constructing ...
Synthesis of iminophosphoranes as ligands for organometallic compounds
(MDPI, 2016)
Iminophosphoranes are organic compounds of general composition R3P=NR and can be considered as nitrogen analogues to phophorus ylides. They can be obtained by the Staudinger and Kirsanov reactions. This compounds have ...
Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline
(MDPI, 2015)
We report here the formation of dimeric palladium(II) and zinc(II) complexes of a ligand (H2L) derived from the condensation of 2 tosylaminomethylaniline and 2,3-dihydroxybenzaldehyde.The structures in solution of the ...
Total Hydrolysis of a New Imidazolidine Induced by ZnII
(MDPI, 2015)
2,2´-(2-(2-hydroxyphenyl)imidazolidin-1,3-diyl)diethanol(H3L) was obtained by condensation between 2-hydroxybenzaldehyde and N,N'-bis(2-hydroxyethyl)ethylenediamine. Its potential ability as NNOOO donor towards ZnII was ...
A heteronuclear ZnGd complex as a potential contrast agent for magnetic resonance imaging
(MDPI, 2016)
A new ligand H3L, with internal compartments for allocating 3d metal ions and external donors to bind 4f ions, was synthesized and completely characterized. Reaction of H3L with zinc(II) and gadolin ium(III) salts allows ...
Functionalized thiosemicarbazone ligands and their complexes
(MDPI, 2016)
The purpose of this work is the design, synthesis and characterization of thiosemicarbazone ligands bearing a phenyl boronic acid functionality. The main interest is the synthesis of organopalladium compounds with the ...
H-Bonded Polymerisation of Alternate Δ and Λ Metallohelicates
(MDPI, 2015)
he neutral cadmium(II) complex Cd(HL)2 (H2L = 2-[(1H-imidazol-2-yl)methyleneamino]phenol) is chiral and it can be considered as a simple metallohelicate, with its corresponding Δ and Λ enantiomers. In the solid state, its ...
Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups
(MDPI, 2015)
The synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, ...