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Functionalized thiosemicarbazone ligands and their complexes
The purpose of this work is the design, synthesis and characterization of thiosemicarbazone ligands bearing a phenyl boronic acid functionality. The main interest is the synthesis of organopalladium compounds with the ...
Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups
The synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, ...
Study of the conformational rearrangement of a tetradentate hydrazone ligand
We report herein the first example of a tetradentate hydrazone structurally studied. The analysis of the conformations of this molecule together with the hydrogen bonding interactions allowed us to investigate the changes ...
Synthesis and X-ray Crystal Structure of the Thiosemicarbazone L bis(4-N-Methyl-Thiosemicarbazone)-4,4'-Diacetylphenylmethane
We report herein the synthesis of the tetradentate thiosemicarbazone ligand bis(4-N-methyl-thiosemicarbazone)-4,4'-diacetylphenylmethane, which is a suitable precursor in supramolecular chemistry for the preparation of ...