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dc.contributor.authorRodríguez Riego, Rafael
dc.contributor.authorArias, Sandra
dc.contributor.authorQuiñoá Cabana, Emilio
dc.contributor.authorRiguera Vega, Ricardo
dc.contributor.authorFreire Iribarne, Félix Manuel
dc.date.accessioned2018-02-01T17:42:20Z
dc.date.available2018-08-14T01:00:08Z
dc.date.issued2017-08-14
dc.identifier.citationRodríguez, R., Arias, S., Quiñoá, E., Riguera, R., & Freire, F. (2017). The role of the secondary structure of helical poly(phenylacetylene)s in the formation of nanoparticles from polymer–metal complexes (HPMCs). Nanoscale, 9(45), 17752-17757. http://dx.doi.org/10.1039/c7nr04829g
dc.identifier.issn2040-3372
dc.identifier.urihttp://hdl.handle.net/10347/16403
dc.description.abstractThe great importance of the secondary structure (compressed/stretched) of helical poly(phenylacetylene)s (PPAs) in the formation of nanostructures (nanospheres and nanotoroids) by complexation with metal ions of diverse valences is demonstrated. PPAs bearing the same chelating units [anilide of (R)-methoxyphenylacetic acid] but displaying different helical scaffolds show great differences in their nanostructuration due to the different secondary structures of their helices despite the analogous ways in which their mono- and divalent metal ions form complexes. This key 3-D structural feature has not been taken into account previously when studying the nanostructuration of helical polymer–metal complexes (HPMCs)
dc.description.sponsorshipWe thank Ministerio de Economía y Competitividad [CTQ2015-70519-P, CTQ2014-61470-EXP], FPI (R. Rodríguez), Fundación Gil Dávila (S. Arias), Xunta de Galicia (Centro singular de investigación de Galicia accreditation 2016-2019, GRC2014/040) and European Union (European Regional Development FundERDF) for financial support
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014-61470-EXP/ES/CATALIZADORES POLIMERICOS CON QUIRALIDAD REVERSIBLE
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-70519-P/ES/ATERIALES QUIROPTICOS MODULABLES A PARTIR DE POLIMEROS INTELIGENTES
dc.rights© Royal Society of Chemistry
dc.titleThe role of the secondary structure of helical poly(phenylacetylene)s in the formation of nanoparticles from polymer–metal complexes (HPMCs)
dc.typeinfo:eu-repo/semantics/article
dc.identifier.DOI10.1039/c7nr04829g
dc.relation.publisherversionhttps://doi.org/10.1039/c7nr04829g
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánica
dc.description.peerreviewedSI


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