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dc.contributor.authorFont Molíns, Marc
dc.contributor.authorCendón Mariño, Borja
dc.contributor.authorSeoane Fernández, Andrés
dc.contributor.authorMascareñas Cid, José Luis
dc.contributor.authorGulías Costa, Moisés
dc.date.accessioned2018-06-07T09:07:29Z
dc.date.available2018-11-04T02:00:10Z
dc.date.issued2018-05-04
dc.identifier.citationFont, M., Cendón, B., Seoane, A., Mascareñas, J., & Gulías, M. (2018). Rhodium(III)-Catalyzed Annulation of 2-Alkenyl Anilides with Alkynes through C−H Activation: Direct Access to 2-Substituted Indolines. Angewandte Chemie International Edition. doi: 10.1002/anie.201802830
dc.identifier.issn1521-3757
dc.identifier.urihttp://hdl.handle.net/10347/16765
dc.description.abstractA Rh(III) complex featuring an electron‐deficient η5‐cyclopentadienyl ligand catalyzes an unusual annulation between alkynes and 2‐alkenylanilides, to form synthetically appealing 2‐substituted indolines. Formally, the process can be viewed as an allylic amination with concomitant hydrocarbonation of the alkyne. Mechanistic experiments indicate that this transformation involves a peculiar Rhodium migration with a concomitant 1,5‐H shift
dc.description.sponsorshipThis work has received financial support from Spanish grants (SAF2016-76689-R and CTQ2016-77047-P), the Xunta de Galicia (ED431C 2017/19, 2015-CP082 and Centro Singular de Investigación de Galicia accreditation 2016-2019, ED431G/09) the European Regional Development Fund (ERDF), and the European Research Council (Advanced Grant No. 340055). The orfeo-cinqa network CTQ2016-81797-REDC is also kindly acknowledged
dc.language.isoeng
dc.publisherWiley
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/340055
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797/ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SAF2016-76689-R/ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797-REDC/ES
dc.rights© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.subjectC-H activation
dc.subjectAnnulation
dc.subjectRhodium
dc.subjectCatalysis
dc.titleRhodium(III)‐Catalyzed Annulation of 2‐Alkenylanilides with Alkynes via C‐H Activation: a Direct Access to 2‐substituted Indolines
dc.typeinfo:eu-repo/semantics/article
dc.identifier.DOI10.1002/anie.201802830
dc.relation.publisherversionhttps://doi.org/10.1002/anie.201802830
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánica
dc.description.peerreviewedSI


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