Communication: Selection rules for tunneling splitting of vibrationally excited levels
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Título: | Communication: Selection rules for tunneling splitting of vibrationally excited levels |
Autor/a: | Siebrand, Willem Smedarchina, Zorka Fernández-Ramos, Antonio |
Centro/Departamento: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares Universidade de Santiago de Compostela. Departamento de Química Física |
Data: | 2013-07-08 |
Editor: | AIP Publishing |
Cita bibliográfica: | Siebrand, W., Smedarchina, Z., & Fernández-Ramos, A. (2013). Communication: Selection rules for tunneling splitting of vibrationally excited levels. The Journal Of Chemical Physics, 139(2), 021101. doi: 10.1063/1.4813002 |
Resumo: | Five symmetry-based selection rules are formulated that relate the tunneling splitting of a vibrationally excited level to that of the ground level in molecules with a symmetric double-minimum potential. The rules, which explain why excited levels frequently have smaller splittings than zero-point levels, are used to interpret the observed and calculated splittings in malonaldehyde |
Descrición: | The following article appeared in The Journal of Chemical Physics 139, 021101 (2013) and may be found at https://doi.org/10.1063/1.4813002 |
Versión do editor: | https://doi.org/10.1063/1.4813002 |
URI: | http://hdl.handle.net/10347/16849 |
DOI: | 10.1063/1.4813002 |
ISSN: | 0031-9228 |
E-ISSN: | 1945-0699 |
Dereitos: | © 2013 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing |
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