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dc.contributor.author | Rodríguez-Lojo, Diego |
dc.contributor.author | Peña Gil, Diego |
dc.contributor.author | Pérez Meirás, María Dolores |
dc.contributor.author | Guitián Rivera, Enrique |
dc.date.accessioned | 2018-07-09T10:20:34Z |
dc.date.available | 2018-07-09T10:20:34Z |
dc.date.issued | 2015-06-11 |
dc.identifier.citation | Peña, D., Pérez, D., Rodríguez-Lojo, D., & Guitián, E. (2015). Straightforward Synthesis of Novel Acene-Based Aryne Precursors. Synlett, 26(11), 1633-1637. doi: 10.1055/s-0034-1381005 |
dc.identifier.issn | 0936-5214 |
dc.identifier.uri | http://hdl.handle.net/10347/16988 |
dc.description.abstract | Large polycyclic o-(trimethylsilyl)aryl triflates are easily obtained by reaction of commercially available bisaryne precursors with cyclopentadienones. The transformation involves controlled generation of one of the aryne functionalities, trapping by Diels–Alder reaction with a dienone, and chelotropic extrusion of CO. The newly synthesized triflates are precursors of acene-based arynes, including a didehydropentacene |
dc.description.sponsorship | Financial support from the Spanish Ministry of Science and Competitiveness (MINECO, CTQ2013-44142-P and MAT2013-46593-C6-6-P), the European Union (Project PAMS, contract no. 610446), Xunta de Galicia (GPC2014/25), and FEDER is gratefully acknowledged. D.R.-L. thanks the Spanish Ministry of Education for the award of an FPU fellowship |
dc.language.iso | eng |
dc.publisher | Thieme Publishing |
dc.rights | © Georg Thieme Verlag Stuttgart · New York |
dc.subject | Arynes |
dc.subject | Polycyclic aromatic hydrocarbons |
dc.subject | Acenes |
dc.subject | Diels–Alder reaction |
dc.subject | Cycloadditions |
dc.title | Straightforward Synthesis of Novel Acene-Based Aryne Precursors |
dc.type | journal article |
dc.identifier.doi | 10.1055/s-0034-1381005 |
dc.relation.publisherversion | https://doi.org/10.1055/s-0034-1381005 |
dc.type.hasVersion | AM |
dc.identifier.essn | 1437-2096 |
dc.rights.accessRights | open access |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
dc.description.peerreviewed | SI |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/610446 |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013-44142-P/ES/NUEVOS RETOS EN LA QUIMICA DE ARINOS: HERRAMIENTAS SINTETICAS EN CIENCIA DE MATERIALES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-46593-C6-6-P/ES/HIBRIDOS COVALENTES EN SUPERFICIES |
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