Mostrar o rexistro simple do ítem
dc.contributor.author | Zuzak, Rafał |
dc.contributor.author | Pozo Míguez, Iago |
dc.contributor.author | Engelund, Mads |
dc.contributor.author | García Lekue, Aran |
dc.contributor.author | Vilas Varela, Manuel |
dc.contributor.author | Alonso, José M. |
dc.contributor.author | Szymonski, Marek |
dc.contributor.author | Guitián Rivera, Enrique Carlos |
dc.contributor.author | Pérez Meirás, María Dolores |
dc.contributor.author | Godlewski, Szymon |
dc.contributor.author | Peña Gil, Diego |
dc.date.accessioned | 2020-04-13T19:45:54Z |
dc.date.available | 2020-04-13T19:45:54Z |
dc.date.issued | 2019 |
dc.identifier.citation | Zuzak, R., Pozo, I., Engelund, M., Garcia-Lekue, A., Vilas-Varela, M., & Alonso, J. et al. (2019). Synthesis and reactivity of a trigonal porous nanographene on a gold surface. Chemical Science, 10(43), 10143-10148. doi: 10.1039/c9sc03404h |
dc.identifier.issn | 2041-6520 |
dc.identifier.uri | http://hdl.handle.net/10347/21330 |
dc.description.abstract | The synthesis of porous nanographenes is a challenging task for solution chemistry, and thus, on-surface synthesis provides an alternative approach. Here, we report the synthesis of a triporous nanographene with 102 sp2 carbon atoms by combining solution and surface chemistry. The carbon skeleton was obtained by Pd-catalyzed cyclotrimerization of arynes in solution, while planarization of the molecule was achieved through two hierarchically organized on-surface cyclodehydrogenation reactions, intra- and inter-blade. Remarkably, the three non-planar [14]annulene pores of this nanographene further evolved at higher temperatures showing interesting intra-porous on-surface reactivity |
dc.description.sponsorship | We acknowledge financial support from the National Science Center, Poland (2017/26/E/ST3/00855), Agencia Estatal de Investigación (MAT2016-78293-C6-3-R and CTQ2016-78157-R), Xunta de Galicia (Centro singular de investigación de Galicia, accreditation 2016–2019, ED431G/09) and Fondo Europeo de Desarrollo Regional (FEDER). IP thanks Xunta de Galicia and the European Union (European Social Fund, ESF) for awarding a pre-doctoral fellowship |
dc.language.iso | eng |
dc.publisher | Royal Society of Chemistry |
dc.rights | Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/3.0/ |
dc.subject | Nanographene |
dc.title | Synthesis and reactivity of a trigonal porous nanographene on a gold surface |
dc.type | journal article |
dc.identifier.doi | 10.1039/c9sc03404h |
dc.relation.publisherversion | https://doi.org/10.1039/c9sc03404h |
dc.type.hasVersion | VoR |
dc.identifier.essn | 2041-6539 |
dc.rights.accessRights | open access |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
dc.description.peerreviewed | SI |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-78293-C6-3-R/ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-78157-R/ES |
Ficheiros no ítem
Este ítem aparece na(s) seguinte(s) colección(s)
-
CIQUS-Artigos [475]
-
QO-Artigos [436]