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dc.contributor.authorZuzak, Rafał
dc.contributor.authorPozo Míguez, Iago
dc.contributor.authorEngelund, Mads
dc.contributor.authorGarcía Lekue, Aran
dc.contributor.authorVilas Varela, Manuel
dc.contributor.authorAlonso, José M.
dc.contributor.authorSzymonski, Marek
dc.contributor.authorGuitián Rivera, Enrique Carlos
dc.contributor.authorPérez Meirás, María Dolores
dc.contributor.authorGodlewski, Szymon
dc.contributor.authorPeña Gil, Diego
dc.date.accessioned2020-04-13T19:45:54Z
dc.date.available2020-04-13T19:45:54Z
dc.date.issued2019
dc.identifier.citationZuzak, R., Pozo, I., Engelund, M., Garcia-Lekue, A., Vilas-Varela, M., & Alonso, J. et al. (2019). Synthesis and reactivity of a trigonal porous nanographene on a gold surface. Chemical Science, 10(43), 10143-10148. doi: 10.1039/c9sc03404h
dc.identifier.issn2041-6520
dc.identifier.urihttp://hdl.handle.net/10347/21330
dc.description.abstractThe synthesis of porous nanographenes is a challenging task for solution chemistry, and thus, on-surface synthesis provides an alternative approach. Here, we report the synthesis of a triporous nanographene with 102 sp2 carbon atoms by combining solution and surface chemistry. The carbon skeleton was obtained by Pd-catalyzed cyclotrimerization of arynes in solution, while planarization of the molecule was achieved through two hierarchically organized on-surface cyclodehydrogenation reactions, intra- and inter-blade. Remarkably, the three non-planar [14]annulene pores of this nanographene further evolved at higher temperatures showing interesting intra-porous on-surface reactivity
dc.description.sponsorshipWe acknowledge financial support from the National Science Center, Poland (2017/26/E/ST3/00855), Agencia Estatal de Investigación (MAT2016-78293-C6-3-R and CTQ2016-78157-R), Xunta de Galicia (Centro singular de investigación de Galicia, accreditation 2016–2019, ED431G/09) and Fondo Europeo de Desarrollo Regional (FEDER). IP thanks Xunta de Galicia and the European Union (European Social Fund, ESF) for awarding a pre-doctoral fellowship
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.rightsOpen Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/
dc.subjectNanographene
dc.titleSynthesis and reactivity of a trigonal porous nanographene on a gold surface
dc.typejournal article
dc.identifier.doi10.1039/c9sc03404h
dc.relation.publisherversionhttps://doi.org/10.1039/c9sc03404h
dc.type.hasVersionVoR
dc.identifier.essn2041-6539
dc.rights.accessRightsopen access
dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánica
dc.description.peerreviewedSI
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-78293-C6-3-R/ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-78157-R/ES


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