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dc.contributor.authorÁlvarez Pérez, Andrea
dc.contributor.authorSaá Rodríguez, Carlos
dc.contributor.authorVarela Carrete, Jesús Ángel
dc.date.accessioned2020-10-05T07:20:13Z
dc.date.available2021-06-15T01:00:09Z
dc.date.issued2020
dc.identifier.citationÁlvarez-Pérez, A., Saá, C., Varela, J. A. (2020). Oxidation of Alkynes via Catalytic Metal-Vinylidenes. Synthesis, 52, 18, 2639-2649
dc.identifier.issn0039-7881
dc.identifier.urihttp://hdl.handle.net/10347/23361
dc.descriptionNOTICE: This is the peer reviewed version of the following article: Álvarez-Pérez, A., Saá, C., Varela, J. A. (2020). Oxidation of Alkynes via Catalytic Metal-Vinylidenes. Synthesis, 52, 18, 2639-2649. [doi: 10.1055/s-0040-1707860]. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archiving
dc.description.abstractMetal-vinylidenes, generated by treatment of terminal alkynes with transition metals, are very useful intermediates in modern synthetic chemistry as shown by the high number of transformations in which they are involved. When a metal-vinylidene is generated in the presence of an oxidant, its immediate oxidation to a ketene intermediate occurred. In this short review, recent synthetic applications of the oxidation of alkynes via ketene intermediates from initially formed metal-vinylidenes are highlighted.
dc.description.sponsorshipThis work has received financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund – ERDF)
dc.language.isoeng
dc.publisherThieme
dc.relationinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CTQ2017-87939-R/ES/NUEVAS RUTAS CATALITICAS A PAHS (HIDROCARBUROS AROMATICOS POLICICLICOS) DOPADOS Y HETEROCICLOS BIOACTIVOS
dc.rights© Georg Thieme Verlag Stuttgart · New York. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archiving
dc.subjectAmides
dc.subjectCyclization
dc.subjectEsters
dc.subjectβ-Lactams
dc.subjectKetenes
dc.subjectVinylidenes
dc.titleOxidation of Alkynes via Catalytic Metal-Vinylidenes
dc.typeinfo:eu-repo/semantics/article
dc.identifier.DOI10.1055/s-0040-1707860
dc.relation.publisherversionhttps://doi.org/10.1055/s-0040-1707860
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.identifier.e-issn1437-210X
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánica
dc.description.peerreviewedSI


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