Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes
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Título: | Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes |
Autor/a: | Chaves Pouso, Andrea Rivera Chao, Eva Fañanás Mastral, Martín |
Centro/Departamento: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares Universidade de Santiago de Compostela. Departamento de Química Orgánica |
Data: | 2020 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | Chaves-Pouso, A., Rivera-Chao, E., & Fañanás-Mastral, M. (2020). Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes. Chemical Communications. https://doi.org/10.1039/d0cc04018e |
Resumo: | A copper-catalyzed protoboration of borylated dendralenes is reported. The method employs an NHC–Cu catalyst and provides access to 1,4-addition products with excellent levels of chemo-, regio- and stereoselectivity. The resulting diene bis(boronates) are oxidized to the corresponding diene diols which are synthetically versatile building blocks |
Versión do editor: | https://doi.org/10.1039/D0CC04018E |
URI: | http://hdl.handle.net/10347/23373 |
DOI: | 10.1039/D0CC04018E |
E-ISSN: | 1364-548X |
Dereitos: | © The Royal Society of Chemistry 2020. This article may be used for non- commercial purposes in accordance with RSC Terms and Conditions for Use of Self-Archived Versions |
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