3-O-Benzyl-6-O-benzoyl-1,2-Oisopropilidene-5-C-nitromethyl-a-Dglucofuranose
xmlui.ArtifactBrowser.ItemViewer.URI
http://hdl.handle.net/10347/23390
Files in this item
 |
|  |
Metadata
| xmlui.metadata.dc.title: | 3-O-Benzyl-6-O-benzoyl-1,2-Oisopropilidene-5-C-nitromethyl-a-Dglucofuranose |
| xmlui.metadata.dc.contributor.author: | Pampín Casal, María Begoña Valencia Matarranz, Laura Estévez Cabanas, Juan Carlos Estévez Cabanas, Ramón José |
| xmlui.metadata.dc.contributor.affiliation: | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
| xmlui.metadata.dc.subject: | Single-crystal X-ray study | T = 113 K | Mean (C–C) = 0.006 A˚ | R factor = 0.047 | wR factor = 0.131 | Data-to-parameter ratio = 8.6. | |
| xmlui.metadata.dc.date.issued: | 2008 |
| xmlui.metadata.dc.publisher: | International Union of Crystallography |
| xmlui.metadata.dc.identifier.citation: | Pampín, Begoña, Valencia, Laura, Estévez, Juan C., Estévez, Ramón J. (2009). 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-D-glucofuranose. "Act. Cryst". vol. 65, o332-o333 |
| xmlui.metadata.dc.description.abstract: | The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-D-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O-H...O hydrogen bond and some intramolecular and intermolecular C-H...O interactions are observed in the structure |
| xmlui.metadata.dc.relation.publisherversion: | https://doi.org/10.1107/S1600536808043353 |
| xmlui.metadata.dc.identifier.uri: | http://hdl.handle.net/10347/23390 |
| xmlui.metadata.dc.identifier.DOI: | 10.1107/S1600536808043353 |
| xmlui.metadata.dc.identifier.issn: | 2056-9890 |
| xmlui.metadata.dc.identifier.e-issn: | 1600-5368 |
| xmlui.metadata.dc.rights: | This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited |
Collections
-
- QO-Artigos [325]
xmlui.mirage2.itemSummaryView.compartir
 |  |
xmlui.mirage2.itemSummaryView.citas
 | ||
 |
Except where otherwise noted, this item's license is described as This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited