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dc.contributor.author | Fernández Fernández, David |
dc.contributor.author | Mascareñas Cid, José Luis |
dc.contributor.author | López García, Fernando |
dc.date.accessioned | 2020-11-03T12:50:28Z |
dc.date.available | 2020-11-03T12:50:28Z |
dc.date.issued | 2020 |
dc.identifier.citation | Chem. Soc. Rev., 2020,49, 7378-7405 |
dc.identifier.uri | http://hdl.handle.net/10347/23537 |
dc.description.abstract | Transition metal-catalyzed hydrocarbonations of unsaturated substrates have emerged as powerful synthetic tools for increasing molecular complexity in an atom-economical manner. Although this field was traditionally dominated by low valent rhodium and ruthenium catalysts, in recent years, there have been many reports based on the use of iridium complexes. In many cases, these reactions have a different course from those of their rhodium homologs, and even allow performing otherwise inviable transformations. In this review we aim to provide an informative journey, from the early pioneering examples in the field, most of them based on other metals than iridium, to the most recent transformations catalyzed by designed Ir(I) complexes. The review is organized by the type of C–H bond that is activated (with C sp2, sp or sp3), as well as by the C–C unsaturated partner that is used as a hydrocarbonation partner (alkyne, allene or alkene). Importantly, we discuss the mechanistic foundations of the methods highlighting the differences from those previously proposed for processes catalyzed by related metals, particularly those of the same group (Co and Rh) |
dc.description.sponsorship | This work received financial support from Spanish grants (SAF2016-76689-R, CTQ2016-77047-P, CTQ2017-84767-P and ORFEO-CINQA network CTQ2016-81797-REDC), the Consellería de Cultura, Educación e Ordenación Universitaria (2015-CP082, ED431C-2017/19 and Centro Singular de Investigación de Galicia accreditation 2019–2022, ED431G 2019/03), the European Union (European Regional Development Fund-ERDF corresponding to the multiannual financial framework 2014–2020), and the European Research Council (Advanced Grant No. 340055). DFF thanks Xunta de Galicia for his postdoctoral fellowship (ED481B-2019-005) |
dc.language.iso | eng |
dc.publisher | Royal Society of Chemistry |
dc.rights | © Royal Society of Chemistry 2020. Open Access Article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/ |
dc.title | Catalytic addition of C–H bonds across C–C unsaturated systems promoted by iridium(i) and its group IX congeners |
dc.type | journal article |
dc.identifier.doi | 10.1039/D0CS00359J |
dc.relation.publisherversion | https://doi.org/10.1039/D0CS00359J |
dc.type.hasVersion | VoR |
dc.identifier.essn | 1460-4744 |
dc.rights.accessRights | open access |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
dc.description.peerreviewed | SI |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/340055 |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797/ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SAF2016-76689-R/ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CTQ2017-84767-P/ES/METODOS SINTETICOS EFICIENTES BASADOS EN CATALISIS METALICA. DESARROLLOS ENANTIOSELECTIVOS Y ACCESO A MOLECULAS BIOACTIVAS Y/O DE ALTO INTERES SINTETICO |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797-REDC/ES |
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