[C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights
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| Title: | [C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights |
| Author: | González, Jorge A. Verdugo Leal, Felipe Ignacio Mascareñas Cid, José Luis López García, Fernando Nevado, Cristina |
| Affiliation: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares Universidade de Santiago de Compostela. Departamento de Química Orgánica |
| Subject: | [C^N] cyclometalated gold(III) | Alkylidenecyclopropanes | C−C activation | Gold | σ-bond metathesis | |
| Date of Issue: | 2020 |
| Publisher: | Wiley |
| Citation: | J. A. González, F. Verdugo, J. L. Mascareñas, F. López, C. Nevado, Angew. Chem. Int. Ed. 2020, 59, 20049 |
| Abstract: | Pyridine‐substituted alkylidenecyclopropanes (Py‐ACPs) react with gold(III) salts under mild reaction conditions through an unprecedented, proximal ring‐opening pathway, to generate highly appealing, catalytically active pyridine alkenyl [C^N]‐gold(III) species. Mechanistic studies reveal that the activation of the C−C bond of the ACP takes place through an unusual concerted, σ‐bond metathesis type‐process |
| Description: | This is the peer reviewed version of the following article: J. A. González, F. Verdugo, J. L. Mascareñas, F. López, C. Nevado, Angew. Chem. Int. Ed. 2020, 59, 20049, which has been published in final form at https://doi.org/10.1002/anie.202007371. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. |
| Publisher version: | https://doi.org/10.1002/anie.202007371 |
| Embargo: | 2021-07-16 |
| URI: | http://hdl.handle.net/10347/23539 |
| DOI: | 10.1002/anie.202007371 |
| ISSN: | 1433-7851 |
| E-ISSN: | 1521-3773 |
| Rights: | © 2020 Wiley-VCH. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions |
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