Show simple item record

dc.contributor.authorGonzález Riopedre, Gustavo
dc.contributor.authorFernández García, María Isabel
dc.contributor.authorGonzález Noya, Ana María
dc.contributor.authorPedrido Castiñeiras, Rosa María
dc.contributor.authorRodríguez Silva, Laura
dc.contributor.authorManeiro Maneiro, Marcelino
dc.identifier.citationGonzález-Riopedre, G., Fernández-García, M.I., González-Noya, A.M., Pedrido, R., Rodríguez, L. & Maneiro, M. (2015). Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-18: The 18Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2014. MDPI. doi: 10.3390/ecsoc-18-a018
dc.descriptionThe 18th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
dc.description.abstractThe synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, is reported. The new synthetic route involves seven steps: 1) obtention of phthalimido-acetal; 2) Acetal deprotection; 3) Synthesis of the salicylamine; 4) Obtention of the benzoxacine; 5) Reduction of the benzoxacine with NaBH3CN; 6) Reduction with hydrazine to form salycilamine; 7) Synthesis of the final ligand by condensation of salicylamine with salycilaldehyde. All organic products were characterised by microanalysis and 1H NMR, IR and mass spectroscopies
dc.relation.ispartofseriesElectronic Conference on Synthetic Organic Chemistry;18
dc.rights© 2015 by MDPI, Basel, Switzerland. Open Access
dc.subjectSchiff base
dc.subjectSynthetic route
dc.subjectAmino group
dc.titleSynthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánica

Files in this item

Name: 2015_ecsoc18_gonzalez_synthetic.pdf
Size: 80.59 Kb
Format: PDF

Name: 2015_ecsoc18_gonzalez_synthetic_presentations.pdf
Size: 248.2 Kb
Format: PDF


This item appears in the following Collection(s)

Show simple item record

Harvesters:Useful links:
Universidade de Santiago de Compostela | Teléfonos: +34 881 811 000 e +34 982 820 000 | Contact Us | Send Feedback