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dc.contributor.authorGonzález Riopedre, Gustavo
dc.contributor.authorFernández García, María Isabel
dc.contributor.authorGonzález Noya, Ana María
dc.contributor.authorPedrido Castiñeiras, Rosa María
dc.contributor.authorRodríguez Silva, Laura
dc.contributor.authorManeiro Maneiro, Marcelino
dc.date.accessioned2021-04-14T13:04:00Z
dc.date.available2021-04-14T13:04:00Z
dc.date.issued2015
dc.identifier.citationGonzález-Riopedre, G., Fernández-García, M.I., González-Noya, A.M., Pedrido, R., Rodríguez, L. & Maneiro, M. (2015). Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-18: The 18Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2014. MDPI. doi: 10.3390/ecsoc-18-a018
dc.identifier.isbn978-3-906980-55-3
dc.identifier.urihttp://hdl.handle.net/10347/25981
dc.descriptionThe 18th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
dc.description.abstractThe synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, is reported. The new synthetic route involves seven steps: 1) obtention of phthalimido-acetal; 2) Acetal deprotection; 3) Synthesis of the salicylamine; 4) Obtention of the benzoxacine; 5) Reduction of the benzoxacine with NaBH3CN; 6) Reduction with hydrazine to form salycilamine; 7) Synthesis of the final ligand by condensation of salicylamine with salycilaldehyde. All organic products were characterised by microanalysis and 1H NMR, IR and mass spectroscopies
dc.language.isoeng
dc.publisherMDPI
dc.relation.ispartofseriesElectronic Conference on Synthetic Organic Chemistry;18
dc.rights© 2015 by MDPI, Basel, Switzerland. Open Access
dc.subjectAsymmetry
dc.subjectLigand
dc.subjectSchiff base
dc.subjectSynthetic route
dc.subjectAmino group
dc.titleSynthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups
dc.typeinfo:eu-repo/semantics/bookPart
dc.identifier.DOI10.3390/ecsoc-18-a018
dc.relation.publisherversionhttps://doi.org/10.3390/ecsoc-18-a018
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánica


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