Synthesis of dicompartimental schiff base ligands : Crystal structure of (n-n'-bis(3- methoxy or 3-ethoxysalicylidene)-1,2-diamine-2-methylpropane
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Título: | Synthesis of dicompartimental schiff base ligands : Crystal structure of (n-n'-bis(3- methoxy or 3-ethoxysalicylidene)-1,2-diamine-2-methylpropane |
Autor/a: | Vázquez Fernández, María de los Ángeles Fernández García, María Isabel Fernández Fernández, Beatriz González Noya, Ana María Rodríguez Doutón, María Jesús |
Centro/Departamento: | Universidade de Santiago de Compostela. Departamento de Química Inorgánica |
Palabras chave: | Supramolecular Chemistry | Dicompartimental Schiff bases | Hydrogen bonds | Manganese | |
Data: | 2010 |
Editor: | MDPI |
Cita bibliográfica: | Proceedings of the 14th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2010, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-14-00437 |
Serie: | Electronic Conference on Synthetic Organic Chemistry;14 |
Resumo: | The condensation of 3-methoxy or 3-ethoxy-2-hydroxybenzaldehyde and 1,2 diamine -2-methylpropane, to yield at the dianionic hexadentate Schiff base ligands H2 Ln (H2 L1 , H2 L2 respectively). The ligands have been characterised by elemental analysis, IR, 1H and 13C NMR spectroscopies and mass spectrometry (ES). The crystal structure of the two ligands was solved by X-ray crystallography, revealing its ability to bind metal centres |
Descrición: | The 14th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis |
Versión do editor: | https://doi.org/10.3390/ecsoc-14-00437 |
URI: | http://hdl.handle.net/10347/26881 |
DOI: | 10.3390/ecsoc-14-00437 |
Dereitos: | © 2010 The author(s). Published by MDPI, Basel, Switzerland. Open Access |