Palladium-Catalyzed Tandem Cycloisomerization/Cross-Coupling of Carbonyl- and Imine-Tethered Alkylidenecyclopropanes
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| Title: | Palladium-Catalyzed Tandem Cycloisomerization/Cross-Coupling of Carbonyl- and Imine-Tethered Alkylidenecyclopropanes |
| Author: | Verdugo Leal, Felipe Ignacio Rodiño Balboa, Ricardo Calvelo Souto, Martín Mascareñas Cid, José Luis López García, Fernando José |
| Affiliation: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares Universidade de Santiago de Compostela. Departamento de Química Orgánica |
| Date of Issue: | 2022 |
| Publisher: | Wiley |
| Citation: | Angew. Chem. Int. Ed. 2022, 61, e20220229 |
| Abstract: | A palladium catalytic system is reported for the divergent tandem cycloisomerization and cross-coupling of carbonyl- and imine-tethered alkylidenecyclopropanes (ACPs). The selection of ancillary ligands is pivotal for the interception of the heteropalladacyclic intermediates with different external nucleophiles |
| Publisher version: | https://doi.org/10.1002/anie.202202295 |
| URI: | http://hdl.handle.net/10347/28826 |
| DOI: | 10.1002/anie.202202295 |
| ISSN: | 0044-8249 |
| E-ISSN: | 1521-3757 |
| Rights: | © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is noncommercial and no modifications or adaptations are made. Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
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Except where otherwise noted, this item's license is described as © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is noncommercial and no modifications or adaptations are made.