Institutos e Centros de Investigación
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Palladium-Catalyzed, Enantioselective Formal Cycloaddition between Benzyltriflamides and Allenes: Straightforward Access to Enantioenriched Isoquinolines
(American Chemical Society, 2019)Benzyl and allyltriflamides can engage in Pd-catalyzed oxidative (4+2) annulations with allenes, to produce highly valuable tetrahydroisoquinoline or dihydropyridine skeletons. The reaction is especially efficient when ... -
Allenes and Derivatives in Gold(I)- and Platinum(II)-Catalyzed Formal Cycloadditions
(American Chemical Society, 2019)Conspectus Cycloaddition reactions, by involving the formation of at least two bonds and one cycle in a single operation, represent one of the more practical ways to assemble carbo- and heterocyclic structures from ... -
Ruthenium-Catalyzed Redox Isomerizations inside Living Cells
(American Chemical Society, 2019)Tailored ruthenium(IV) complexes can catalyze the isomerization of allylic alcohols into saturated carbonyl derivatives under physiologically relevant conditions, and even inside living mammalian cells. The reaction, which ... -
A crosslinguistic study of voiceless fricative sibilants in Galician and European Portuguese
(Oxford University Press, 2019)This study examines the sibilant fricatives produced by seventeen Galician and twenty-two Portuguese speakers. Galician and Portuguese are closely related languages that present important continuities, although it is in ... -
A New Approach for Sparse Matrix Classification Based on Deep Learning Techniques
(IEEE, 2018)In this paper, a new methodology to select the best storage format for sparse matrices based on deep learning techniques is introduced. We focus on the selection of the proper format for the sparse matrix-vector multiplication ...
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