Merging supramolecular and covalent helical polymers: four helices within a single scaffold
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Título: | Merging supramolecular and covalent helical polymers: four helices within a single scaffold |
Autor/a: | Fernández Villar, Zulema Fernández Rodríguez, Berta Quiñoá Cabana, Emilio Freire Iribarne, Félix Manuel |
Centro/Departamento: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares Universidade de Santiago de Compostela. Departamento de Química Física Universidade de Santiago de Compostela. Departamento de Química Orgánica |
Palabras chave: | Chemical structure | Circular dichroism spectroscopy | Materials | Polymer scaffolds | Polymers | |
Data: | 2021 |
Editor: | ACS Publications |
Cita bibliográfica: | J. Am. Chem. Soc. 2021, 143, 20962–20969. https://doi.org/10.1021/jacs.1c10327 |
Resumo: | Supramolecular and covalent polymers share multiple structural effects such as chiral amplification, helical inversion, sergeants and soldiers, or majority rules, among others. These features are related to the axial helical structure found in both types of materials, which are responsible for their properties. Herein a novel material combining information and characteristics from both fields of helical polymers, supramolecular (oligo(p-phenyleneethynylene) (OPE)) and covalent (poly(acetylene) (PA)), is presented. To achieve this goal, the poly(acetylene) must adopt a dihedral angle between conjugated double bonds (ω1) higher than 165°. In such cases, the tilting degree (Θ) between the OPE units used as pendant groups is close to 11°, like that observed in supramolecular helical arrays of these molecules. Polymerization of oligo[(p-phenyleneethynylene)n]phenylacetylene monomers (n = 1, 2) bearing L-decyl alaninate as the pendant group yielded the desired scaffolds. These polymers adopt a stretched and almost planar polyene helix, where the OPE units are arranged describing a helical structure. As a result, a novel multihelix material was prepared, the ECD spectra of which are dominated by the OPE axial array |
Versión do editor: | https://pubs.acs.org/doi/10.1021/jacs.1c10327. |
URI: | http://hdl.handle.net/10347/29026 |
DOI: | 10.1021/jacs.1c10327 |
ISSN: | 0002-7863 |
Dereitos: | © 2021 American Chemical Society. This work is licenced under a Creative Commons Attribution 4.0 International licence (https://creativecommons.org/licenses/by/4.0/legalcode |
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