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dc.contributor.author | Castro-Esteban, Jesús |
dc.contributor.author | Albrecht, Florian |
dc.contributor.author | Fatayer, Shadi |
dc.contributor.author | Pérez Meirás, María Dolores |
dc.contributor.author | Gross, Leo |
dc.contributor.author | Peña Gil, Diego |
dc.date.accessioned | 2022-08-11T10:56:08Z |
dc.date.available | 2022-08-11T10:56:08Z |
dc.date.issued | 2021 |
dc.identifier.citation | Angew. Chem. Int. Ed. 2021, 60, 26346 – 26350. https://doi.org/10.1002/anie.202110311 |
dc.identifier.issn | 1433-7851 |
dc.identifier.uri | http://hdl.handle.net/10347/29052 |
dc.description.abstract | The Diels–Alder reaction is one of the most popular reactions in organic chemistry. However, its use in the field of on-surface synthesis is hampered by the spatial restrictions of this cycloaddition reaction. Herein we selected a cyclic strained triyne to demonstrate an on-surface hexadehydro-Diels–Alder reaction in a single molecule. The reaction was studied in detail by means of atomic force microscopy (AFM) with CO-functionalized tips. Our results pave the way to use this iconic pericyclic reaction for on-surface synthesis, introducing the concept of atom economy in the field |
dc.description.sponsorship | We thank Rolf Allenspach and Enrique Guitián for discussions. We thank the European Union (Project SPRING, contract no. 863098), the ERC grant AMSEL (682144), the Spanish Agencia Estatal de Investigación (PID2019-107338RB-C62, PID2019-110037GB-I00 and PCI2019-111933-2), Xunta de Galicia (Centro de Investigación de Galicia accreditation 2019–2022, ED431G 2019/03) and the European Regional Development Fund-ERDF for financial support |
dc.language.iso | eng |
dc.publisher | Wiley |
dc.rights | ©2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is noncommercial and no modifications or adaptations are made |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.subject | Bond-resolved AFM |
dc.subject | Cycloaddition |
dc.subject | Diels–Alder reaction |
dc.subject | On-surface synthesis |
dc.subject | Polycyclic aromatic hydrocarbons |
dc.title | An on-surface Diels–Alder reaction |
dc.type | journal article |
dc.identifier.doi | 10.1002/anie.202110311 |
dc.relation.publisherversion | https://doi.org/10.1002/anie.202110311 |
dc.type.hasVersion | VoR |
dc.identifier.essn | 1521-3773 |
dc.rights.accessRights | open access |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares |
dc.contributor.affiliation | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
dc.description.peerreviewed | SI |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PCI2019-111933-2/SINTESIS EN DISOLUCION PARA LA INTEGRACION DEL GRAFENO NANOPOROSO MULTIFUNCIONAL EN BIOSENSORES NANOFOTONICOS |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/863098 |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/682144 |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107338RB-C62/ES/SINTESIS EN DISOLUCION PARA SISTEMAS MOLECULARES FUNCIONALES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-110037GB-I00/LEGO MOLECULAR BASADO EN ARINOS: APLICACION A LA SINTESIS DE HIDROCARBUROS POLICICLICOS CONJUGADOS Y MATERIALES FUNCIONALES |
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©2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is noncommercial and no modifications or adaptations are made
©2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is noncommercial and no modifications or adaptations are made