Recent Submissions

  • Synthetic Route to Novel Asymmetric Tetradentate Ligands Containing Both Amino and Imino Groups 

    González Riopedre, Gustavo; Fernández García, María Isabel; González Noya, Ana María; Pedrido Castiñeiras, Rosa María; Rodríguez Silva, Laura; Maneiro Maneiro, Marcelino (MDPI, 2015)
    The synthesis of a new asymmetric ligand (E)-4-bromo-2-(((2-((5-bromo-2-hydroxybenzyl)(methyl)amino)ethyl)imino)methyl)phenol, which was conceived to model the asymmetry in the active site of peroxidase/catalase mimics, ...
  • H-Bonded Polymerisation of Alternate Δ and Λ Metallohelicates 

    García Deibe, Ana María; Portela García; Portela García, Cristina; Fondo Busto, María Matilde; Sanmartín Matalobos, Jesús (MDPI, 2015)
    he neutral cadmium(II) complex Cd(HL)2 (H2L = 2-[(1H-imidazol-2-yl)methyleneamino]phenol) is chiral and it can be considered as a simple metallohelicate, with its corresponding Δ and Λ enantiomers. In the solid state, its ...
  • Computational and Experimental Studies Into the Conformations of a Triptycene-Based Ditopic Ligand 

    Sanmartín Matalobos, Jesús; García Deibe, Ana María; Amoza Dávila, Martín; Fondo Busto, María Matilde; Mota, Antonio J.; Bhowmick, Sourav; Das, Neeladri (MDPI, 2015)
    We present a combined computational and experimental study of the possible conformations adopted by a ditopic Schiff base ligand based on triptycene. We have performed DFT calculations on a Y-shaped Schiff base ligand ...
  • Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline 

    Sanmartín Matalobos, Jesús; Portela García, Cristina; Fondo Busto, María Matilde; García Deibe, Ana María (MDPI, 2015)
    We report here the formation of dimeric palladium(II) and zinc(II) complexes of a ligand (H2L) derived from the condensation of 2 tosylaminomethylaniline and 2,3-dihydroxybenzaldehyde.The structures in solution of the ...
  • Synthesis and Characterization of a New Triptycene-Based Tripod 

    Sanmartín Matalobos, Jesús; García Deibe, Ana María; Fondo Busto, María Matilde; Pérez Lustres, José Luis; Bhowmick, Sourav; Das, Neeladri (MDPI, 2015)
    Herein, we report an efficient and facile synthesis of a new triptycene based tripodal ligand containing both imine functionality and phenolic pendant arms. This tripodal unit is a potential building block for constructing ...

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